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Physical and Chemical Equilibrium for Chemical Engineers
Noel de Nevers,
Univ. of Utah, Salt Lake City
ISBN: 978-0-471-07170-9
©2002
496 pages
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Detailed Contents
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Preface.
About the Author.
Nomenclature.
Introduction to Equilibrium.
Basic Thermodynamics.
The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules.
Minimization of Gibbs Free Energy.
Vapor Pressure, The Clapeyron Equation, and Single Pure Chemical Species Phase Equilibrium.
Partial Molal Properties.
Fugacity, Ideal Solutions, Activity, Activity Coefficient.
Vapor-Liquid Equilibrium (VLE) at Low Pressures.
Correlating and Predicting Nonideal VLE.
Vapor Liquid Equilibrium (VLE) at High Pressures.
Liquid-Liquid, Liquid-Solid and Gas-Solid Equilibrium.
Chemical Equilibrium.
Equilibrium in Complex Chemical Reactions.
Equilibrium with Gravity or Centrifugal Force, Osmotic Equilibrium, Equilibrium with Surface Tension.
The Phase Rule.
Appendix A: Useful Tables and Charts.
Appendix B: Equilibrium at Other Constraints, Approach to Equilibrium.
Appendix C: The Mathematics of Fugacity, Ideal Solutions, Activity and Activity Coefficients.
Appendix D: Equations of State for Liquids and Solids Well Below Their Critical Temperatures.
Appendix E: Free Energy of Formation Values.
Appendix F: Calculation of Fugacities from Pressure-Explicit EOSs.
Appendix G: Answers to Selected Problems.
Index.
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