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Physical and Chemical Equilibrium for Chemical Engineers
Noel de Nevers,
Univ. of Utah, Salt Lake City
ISBN: 978-0-471-07170-9
©2002
496 pages
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Table of Contents
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- Nomenclature.
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Introduction to Equilibrium.
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Basic Thermodynamics.
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The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules.
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Minimization of Gibbs Free Energy.
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Vapor Pressure, The Clapeyron Equation, and Single Pure Chemical Species Phase Equilibrium.
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Partial Molal Properties.
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Fugacity, Ideal Solutions, Activity, Activity Coefficient.
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Vapor-Liquid Equilibrium (VLE) at Low Pressures.
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Correlating and Predicting Nonideal VLE.
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Vapor Liquid Equilibrium (VLE) at High Pressures.
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Liquid-Liquid, Liquid-Solid and Gas-Solid Equilibrium.
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Chemical Equilibrium.
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Equilibrium in Complex Chemical Reactions.
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Equilibrium with Gravity or Centrifugal Force, Osmotic Equilibrium, Equilibrium with Surface Tension.
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The Phase Rule.
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Appendix A: Useful Tables and Charts.
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Appendix B: Equilibrium at Other Constraints, Approach to Equilibrium.
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Appendix C: The Mathematics of Fugacity, Ideal Solutions, Activity and Activity Coefficients.
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Appendix D: Equations of State for Liquids and Solids Well Below Their Critical Temperatures.
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Appendix E: Free Energy of Formation Values.
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Appendix F: Calculation of Fugacities from Pressure-Explicit EOSs.
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Appendix G: Answers to Selected Problems.
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